Uncategorized
What characteristics define a chemical system in equilibrium?
Equality of forward and reverse rates.
For the reaction,
##A+BrarrC+D##;
there is a forward rate, ##K_f[A][B]##; and a reverse rate, ##K_r[C][D]##.
Equilibrium is defined the equality of forward and reverse rates.
i.e. ##K_f[A][B]####=####K_r[C][D]##
Or, ##K_f/K_r## ##=## ##([C][D])/([A][B])##
And ##K_f/K_r## ##=## ##K_(eq)##, ##”the equilibrium constant“##.